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Hexafluoro-1,3-butadiene

Hexafluoro-1,3-butadiene is a liquefied gas, toxic, flammable, N.O.S. It is is an environmentally friendly dry etching gas with low GWP, high etching rate, high selectivity and high aspect ratio, showing very high performance for critical plasma etching in semiconductor devices manufacturing.

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Hexafluoro-1,3-butadiene

Formula: C₄F₆

What is Hexafluoro-1,3-butadiene?

Hexafluoro-1,3-butadiene is an environmentally friendly dry etching gas with low GWP, high etching rate, high selectivity, and high aspect ratio.

Hexafluorobutadiene (C₄F₆) is a fluorinated hydrocarbon compound that has a number of applications in the semiconductor industry, particularly in the area of etching. Here are some of the key applications of hexafluorobutadiene in semiconductor etching:

Reactive ion etching (RIE): Hexafluorobutadiene is often used as a feed gas in RIE, which is a dry etching process that uses plasma to remove material from a substrate. The high reactivity and low toxicity of C₄F₆ make it an ideal candidate for this process.

Deep reactive ion etching (DRIE): In DRIE, C₄F₆ is used as a passivation gas to protect the sidewalls of the etched features from being etched further. This helps to create high-aspect ratio structures with precise dimensions.

Plasma-enhanced chemical vapor deposition (PECVD): C₄F₆ can be used as a precursor in PECVD, which is a process that deposits thin films of material onto a substrate using plasma. The use of C₄F₆ in PECVD can result in the deposition of high-quality fluorinated films with good conformality.

Chamber cleaning: C4F6 can also be used to clean the chambers of etching equipment. Its high reactivity and low toxicity make it an effective and safe cleaning agent.

Overall, hexafluorobutadiene is a versatile compound that has a number of important applications in the semiconductor industry, particularly in the area of etching. Its unique properties make it an important component in many etching processes, helping to create high-quality structures and devices.

Applications
Specifications
Further Specifications
Cylinder Sizes
  • Used for critical plasma etching in semiconductor devices manufacturing.
Grade 3 Grade 4
Purity 99.9% 99.99%
Nitrogen < 200 ppmv < 40 ppmv
Oxygen, Argon < 100 ppmv < 10 ppmv
Carbon Dioxide < 100 ppmv < 20 ppmv
Moisture < 20 ppmv < 20 ppmv
Other Fluorocarbons < 800 ppmv < 200 ppmv
Isopropylalcohol < 50 ppmv < 20 ppmv
Other Hydrocarbons < 500 ppmv < 250 ppmv
Hydrogen Fluoride < 50 ppmv <10 ppmv
Chemical & Physical Properties
Molecular Weight 162.034
Pressure @ 70°F 25 psig
Valve Outlet CGA 350 DISS 724
Shipping Information
DOT Name 1,3 Hexafluorobutadiene
Hazard Class 2.3, 2.1
DOT No. UN 3160
DOT Label Toxic, Flammable, Inhalation Hazard Zone B
CAS No. 685-63-2
Cylinder Size Fill Weight (lb)
44L/Size 200 99
16L/Size 80 30
7L/Size 35 11

FAQs about Hexafluoro-1,3-butadiene

Is hexafluoro-1,3-butadiene gas safe?

Hexafluoro-1,3-butadiene gas is toxic and flammable, may explode if heated, and has the threat of asphyxia if inhaled.  EFC’s culture of safety ensures that hexafluoro-1,3-butadiene is always handled correctly, safely, and according to industry standards. 

How is hexafluoro-1,3-butadiene gas sold?

Hexafluoro-1,3-butadiene is sold in a compressed, liquified format. 

**Moisture level guaranteed only when Electronic Fluorocarbons prepares the cylinders.
All concentrations are on a mol/mol basis unless otherwise stated.
Product sold on the basis of total impurities. Individual impurities may vary slightly.

*This gas not available for purchase online.